In the history of science, the principle of maximum work was a postulate concerning the relationship between chemical reactions, heat evolution, and the potential work produced there from. The principle was developed in approximate form in 1875 by French chemist Marcellin Berthelot, in the field of thermochemistry, and then later in 1876 by American mathematical physicist Willard Gibbs, in the field of thermodynamics, in a more accurate form. Berthelot's version was essentially: "every pure chemical reaction is accompanied by evolution of heat." (and that this yields the maximum amount of work). The effects of irreversibility, however, showed this version to be incorrect. This was rectified, in thermodynamics, by incorporating the concept of entropy.
Read more about Principle Of Maximum Work: Overview, Thermochemistry, Thermodynamics, See Also
Famous quotes containing the words principle of, principle, maximum and/or work:
“The principle of fashion is ... the principle of the kaleidoscope. A new year can only bring us a new combination of the same elements; and about once in so often we go back and begin again.”
—Katharine Fullerton Gerould (1879–1944)
“I ... observed the great beauty of American government to be, that the simple machines of representation, carried through all its parts, gives facility for a being moulded at will to fit with the knowledge of the age; that thus, although it should be imperfect in any or all of its parts, it bears within it a perfect principle the principle of improvement.
”
—Frances Wright (1795–1852)
“I had a quick grasp of the secret to sanity—it had become the ability to hold the maximum of impossible combinations in one’s mind.”
—Norman Mailer (b. 1923)
“Say what you will, making marriage work is a woman’s business. The institution was invented to do her homage; it was contrived for her protection. Unless she accepts it as such—as a beautiful, bountiful, but quite unequal association—the going will be hard indeed.”
—Phyllis McGinley (1905–1978)