Structure and Synthesis
The molecule has C3v symmetry. It is a derivative of the tetrahedral (P4) unit from insertion of sulfur into three P-P bonds. The P-S and P-P distances are 2.090 and 2.235 Å, respectively. P4Se3 and P4S3 adopt the same structures. These compounds can be melted together and form mixed crystals of one dissolved in the other. Under higher temperatures, mixed chalcogenide molecules P4S2Se and P4SSe2 will form.
P4S3 is produced by the reaction of red or white phosphorus with sulfur. Excess sulfur gives phosphorus pentasulfide (P4S10). It is estimated that 150 ton/y were produced in 1989.
Read more about this topic: Phosphorus Sesquisulfide
Famous quotes containing the words structure and/or synthesis:
“Just as a new scientific discovery manifests something that was already latent in the order of nature, and at the same time is logically related to the total structure of the existing science, so the new poem manifests something that was already latent in the order of words.”
—Northrop Frye (b. 1912)
“In order to begin an analysis, there must already be a synthesis present in the mind.”
—Johan Huizinga (1872–1945)