Structure and Synthesis
The molecule has C3v symmetry. It is a derivative of the tetrahedral (P4) unit from insertion of sulfur into three P-P bonds. The P-S and P-P distances are 2.090 and 2.235 Å, respectively. P4Se3 and P4S3 adopt the same structures. These compounds can be melted together and form mixed crystals of one dissolved in the other. Under higher temperatures, mixed chalcogenide molecules P4S2Se and P4SSe2 will form.
P4S3 is produced by the reaction of red or white phosphorus with sulfur. Excess sulfur gives phosphorus pentasulfide (P4S10). It is estimated that 150 ton/y were produced in 1989.
Read more about this topic: Phosphorus Sesquisulfide
Famous quotes containing the words structure and, structure and/or synthesis:
“Each structure and institution here was so primitive that you could at once refer it to its source; but our buildings commonly suggest neither their origin nor their purpose.”
—Henry David Thoreau (1817–1862)
“There is no such thing as a language, not if a language is anything like what many philosophers and linguists have supposed. There is therefore no such thing to be learned, mastered, or born with. We must give up the idea of a clearly defined shared structure which language-users acquire and then apply to cases.”
—Donald Davidson (b. 1917)
“It is not easy to construct by mere scientific synthesis a foolproof system which will lead our children in a desired direction and avoid an undesirable one. Obviously, good can come only from a continuing interplay between that which we, as students, are gradually learning and that which we believe in, as people.”
—Erik H. Erikson (20th century)