Phenol Formaldehyde Resin - Novolacs

Novolacs

Novolacs are phenol-formaldehyde resins with a formaldehyde to phenol molar ratio of less than one. The polymerization is brought to completion using acid-catalysis such as oxalic acid, hydrochloric acid or sulfonate acids. The phenol units are mainly linked by methylene and/or ether groups. Novolacs are commonly used as photoresists. See also photolithography. The molecular weights are in the low thousands, corresponding to about 10-20 phenol units.

Hexamethylenetetramine or "hexamine" is a hardener added to crosslink novolac. At a temperature >90 °C, it forms methylene and dimethylene amino bridges.

Read more about this topic:  Phenol Formaldehyde Resin