Explanation
Optical rectification can be intuitively explained in terms of the symmetry properties of the non-linear medium: in the presence of a preferred internal direction, the polarization will not reverse its sign at the same time as the driving field. If the latter is represented by a sinusoidal wave, then an average DC polarization will be generated.
Optical rectification is analogous to the electric rectification effect produced by diodes, wherein an AC signal can be converted ("rectified") to DC. However, it is not the same thing. A diode can turn a sinusoidal electric field into a DC current, while optical rectification can turn a sinusoidal electric field into a DC polarization, but not a DC current. On the other hand, a changing polarization is a kind of current. Therefore, if the incident light is getting more and more intense, optical rectification causes a DC current, while if the light is getting less and less intense, optical rectification causes a DC current in the opposite direction. But again, if the light intensity is constant, optical rectification cannot cause a DC current.
When the applied electric field is delivered by a femtosecond-pulse-width laser, the spectral bandwidth associated with such short pulses is very large. The mixing of different frequency components produces a beating polarization, which results in the emission of electromagnetic waves in the terahertz region. The EOR effect is somewhat similar to a classical electrodynamic emission of radiation by an accelerating/decelerating charge, except that here the charges are in a bound dipole form and the THz generation depends on the second order susceptibility of the nonlinear optical medium. A popular material for generating radiation in the 0.5–3 THz range (1 mm wavelength) is zinc telluride.
Optical rectification also occurs on metal surfaces by similar effect as surface second harmonic generation. The effect is however influenced e. g. by nonequilibrium electron excitation and generally it manifests in a more complicated way.
Similar to other nonlinear optical processes, optical rectification is also reported to become enhanced when surface plasmons are excited on a metal surface.
Read more about this topic: Optical Rectification
Famous quotes containing the word explanation:
“There is no explanation for evil. It must be looked upon as a necessary part of the order of the universe. To ignore it is childish, to bewail it senseless.”
—W. Somerset Maugham (1874–1965)
“Young children constantly invent new explanations to account for complex processes. And since their inventions change from week to week, furnishing the “correct” explanation is not quite so important as conveying a willingness to discuss the subject. Become an “askable parent.””
—Ruth Formanek (20th century)
“Herein is the explanation of the analogies, which exist in all the arts. They are the re-appearance of one mind, working in many materials to many temporary ends. Raphael paints wisdom, Handel sings it, Phidias carves it, Shakspeare writes it, Wren builds it, Columbus sails it, Luther preaches it, Washington arms it, Watt mechanizes it. Painting was called “silent poetry,” and poetry “speaking painting.” The laws of each art are convertible into the laws of every other.”
—Ralph Waldo Emerson (1803–1882)