Principle
In NMR, nuclei with spin ≥ 1/2 have a magnetic dipole moment so that their energies are split by a magnetic field, allowing resonance absorption of energy related to the difference between the ground state energy and the excited state. In NQR, on the other hand, nuclei with spin ≥ 1, such as 14N, 35Cl and 63Cu, also have an electric quadrupole moment so that their energies are split by an electric field gradient, created by the electronic bonds in the local environment. This quadrupole moment is associated with non-spherical charge distribution. Since unlike NMR, NQR is done in an environment without a static (or DC) magnetic field, it is sometimes called "zero field NMR". Many NQR transition frequencies depend strongly upon temperature.
Any nucleus with more than one unpaired nuclear particle (protons or neutrons) will have a charge distribution which results in an electric quadrupole moment. Allowed nuclear energy levels are shifted unequally due to the interaction of the nuclear charge with an electric field gradient supplied by the non-uniform distribution electron density (e.g. from bonding electrons) and/or surrounding ions. The NQR effect results when transitions are induced between these nuclear levels by an externally applied radio frequency (RF) magnetic field. This magnetic field is often induced by a solenoid. So the most important difference between NMR and NQR is that in NQR we get magnetic resonance without using a magnet. The technique is very sensitive to the nature and symmetry of the bonding around the nucleus. The energy level shifts are much larger than the chemical shifts measured in NMR. Due to symmetry, the shifts become averaged to zero in the liquid phase, so NQR spectra can only be measured for solids.
Read more about this topic: Nuclear Quadrupole Resonance
Famous quotes containing the word principle:
“The mode of founding a college is, commonly, to get up a subscription of dollars and cents, and then, following blindly the principles of a division of labor to its extreme,—a principle which should never be followed but with circumspection,—to call in a contractor who makes this a subject of speculation,... and for these oversights successive generations have to pay.”
—Henry David Thoreau (1817–1862)
“There is no teaching until the pupil is brought into the same state or principle in which you are; a transfusion takes place; he is you, and you are he; then is a teaching; and by no unfriendly chance or bad company can he ever lose the benefit.”
—Ralph Waldo Emerson (1803–1882)
“Now, what I want is, Facts. Teach these boys and girls nothing but Facts. Facts alone are wanted in life. Plant nothing else, and root out everything else. You can only form the minds of reasoning animals upon Facts: nothing else will ever be of any service to them. This is the principle on which I bring up my own children, and this is the principle on which I bring up these children. Stick to Facts, sir!”
—Charles Dickens (1812–1870)