Typical Ligands That Often Behave As Redox Non-Innocent Ligands
- O2 and NO.
Ligands with extended pi-delocalization such as porphyrins and phthalocyanines, ligands with the generalised formulas 2- or D=CR-CR=D (D = O, S, NR’ and R, R' = alkyl or aryl), and similar related systems are often non-innocent. For example:
- dioxalenes, such as catecholates.
- dithiolenes, such as 1,2-maleonitriledithiolate
- diimines such as derivatives of 1,2-diaminobenzene, α-diimines, and dimethylglyoxime.
- pyridine-2,6-diimine ligands (relevant in polymerisation and hydrogenation catalysis).
The pyridine-2,6-diimine ligand can be easily reduced by one or two electrons.
Read more about this topic: Non-innocent Ligand
Famous quotes containing the words typical and/or behave:
“It is indeed typical that you Earth people refuse to believe in the superiority of any world but your own. Children looking into a magnifying glass, imagining the image you see is the image of your true size.”
—Franklin Coen. Joseph Newman. The Monitor (Douglas Spencer)
“Unless they are immediate victims, the majority of mankind behaves as if war was an act of God which could not be prevented; or they behave as if war elsewhere was none of their business. It would be a bitter cosmic joke if we destroy ourselves due to atrophy of the imagination.”
—Martha Gellhorn (b. 1908)