2011
At the 2011 Australian Open, Niculescu defeated Timea Bacsinszky in straight sets, 6–0, 6–3. Facing off against the 32nd seed, Tsvetana Pironkova of Bulgaria, Niculescu cruised through the match winning 6–4, 6–1. In the third round, she lost to the 2010 French Open champion Francesca Schiavone, 0–6, 6–7.
Niculescu defeated Patricia Mayr-Achleitner in the first round and compatriot Alexandra Dulgheru in the second round, 6–3, 6–0, to advance to the third round of the 2011 US Open. In defeating Lucie Safarova, 6–0, 6–1, Niculescu advanced to the fourth round of a Grand Slam singles competition for the first time in her career, where she lost 4–6, 3–6 to unseeded Angelique Kerber.
At the Tier 1 China Open, she shocked the world with a dominating victory over fourth seed Li Na, 6–4, 6–0 in the first round and advanced to the semifinals, where she lost to eventual runner-up, Andrea Petkovic.
She advanced to her first WTA final at the International tournament in Luxembourg, losing to Victoria Azarenka, 2–6, 2–6. En route to the final, she spent many hours on court with a 6–7, 7–5, 7–6 first-round victory over Karin Knapp, a second-round 7–6, 3–6, 6–1 win over Anabel Medina Garrigues, and a 7–5, 4–6, 6–3 win in 3 hours over 2010 finalist Anne Keothavong in the semifinals.
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