2010
In 2010, Monica started the season in Auckland, coming from qualifying. In the first round, she lost to fifth seed 5 Virginie Razzano, 5–7, 4–6. In doubles, she partnered Ioana Raluca Olaru, and they defeated Anabel Medina Garrigues and Carla Suárez Navarro, 7–5, 7–5. In the second round, they lost to Cara Black and Liezel Huber, 3–6, 2–6.
At the Australian Open, she lost in the first round to Jelena Janković, 4–6, 0–6. In doubles, she partnered Chan Yung-jan and defeated Monique Adamczak and Nicole Kriz, 6–3, 6–1. The pair defeated Alla Kudryavtseva and Ekaterina Makarova in the second round, 6–4, 6–4. In the third round, the lost to sixth seeds Lisa Raymond and Rennae Stubbs, 5–7, 3–6.
Niculescu then played an ITF tournament in Midland, but lost in the first round to Eleni Daniilidou 4–6, 2–6.
In Memphis, she lost in the first round qualifying to Valérie Tétreault. In doubles, she reached the semifinals along with Riza Zalameda, losing to Vania King and Michaëlla Krajicek, 1–6, 4–6.
At Indian Wells, she lost in qualifying to Tamarine Tanasugarn. In doubles, together with Michaëlla Krajicek, she lost in first round to Bethanie Mattek-Sands and Yan Zi, 6–7, 2–6.
In Marbella failed to qualify in singles, but in doubles she partnered Sophie Lefèvre. They defeated Kristina Barrois and Ioana Raluca Olaru in the first round, 6–3, 4–6, . However, in the second round, they lost to Virginia Ruano Pascual and Meghann Shaughnessy, 2–6, 4–6.
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