Metal-organic Framework - Common Ligands in MOFs

Common Ligands in MOFs

Common name IUPAC name Chemical formula Structural formula
Bidentate Carboxylics
Oxalic acid ethanedioic acid HOOC-COOH
Malonic acid propanedioic acid HOOC-(CH2)-COOH
Succinic acid butanedioic acid HOOC-(CH2)2-COOH
Glutaric acid pentanedioic acid HOOC-(CH2)3-COOH
Phthalic acid benzene-1,2-dicarboxylic acid
o-phthalic acid
C6H4(COOH)2
Isophthalic acid benzene-1,3-dicarboxylic acid
m-phthalic acid
C6H4(COOH)2
Terephthalic acid benzene-1,4-dicarboxylic acid
p-phthalic acid
C6H4(COOH)2
Tridentate Carboxylates
Citric Acid 2-Hydroxy-1,2,3-propanetricarboxylic acid (HOOC)CH2C(OH)(COOH)CH2(COOH)
Trimesic acid benzene-1,3,5-tricarboxylic acid C9H6O6
Azoles
1,2,3-Triazole 1H-1,2,3-triazole C2H3N3
pyrrodiazole 1H-1,2,4-triazole C2H3N3
Other
Squaric acid 3,4-Dihydroxy-3-cyclobutene-1,2-dione C4H2O4

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