Metal-organic Framework - Common Ligands in MOFs

Common Ligands in MOFs

Common name IUPAC name Chemical formula Structural formula
Bidentate Carboxylics
Oxalic acid ethanedioic acid HOOC-COOH
Malonic acid propanedioic acid HOOC-(CH2)-COOH
Succinic acid butanedioic acid HOOC-(CH2)2-COOH
Glutaric acid pentanedioic acid HOOC-(CH2)3-COOH
Phthalic acid benzene-1,2-dicarboxylic acid
o-phthalic acid
C6H4(COOH)2
Isophthalic acid benzene-1,3-dicarboxylic acid
m-phthalic acid
C6H4(COOH)2
Terephthalic acid benzene-1,4-dicarboxylic acid
p-phthalic acid
C6H4(COOH)2
Tridentate Carboxylates
Citric Acid 2-Hydroxy-1,2,3-propanetricarboxylic acid (HOOC)CH2C(OH)(COOH)CH2(COOH)
Trimesic acid benzene-1,3,5-tricarboxylic acid C9H6O6
Azoles
1,2,3-Triazole 1H-1,2,3-triazole C2H3N3
pyrrodiazole 1H-1,2,4-triazole C2H3N3
Other
Squaric acid 3,4-Dihydroxy-3-cyclobutene-1,2-dione C4H2O4

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    If music in general is an imitation of history, opera in particular is an imitation of human willfulness; it is rooted in the fact that we not only have feelings but insist upon having them at whatever cost to ourselves.... The quality common to all the great operatic roles, e.g., Don Giovanni, Norma, Lucia, Tristan, Isolde, Brünnhilde, is that each of them is a passionate and willful state of being. In real life they would all be bores, even Don Giovanni.
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