Mass Attenuation Coefficient - Calculating The Composition of A Solution

Calculating The Composition of A Solution

If several known chemicals are dissolved in a single solution, the concentrations of each can be calculated using a light absorption analysis. First, the mass attenuation coefficients of each individual solute or solvent, ideally across a broad spectrum of wavelengths, must be measured or looked up. Second, the attenuation coefficient of the actual solution must be measured. Finally, using the formula

the spectrum can be fitted using as adjustable parameters. (Remember, and each are functions of wavelength.)

If there are N solutes or solvents, this procedure requires at least N measured wavelengths to create a solvable system of simultaneous equations, although using more wavelengths gives more reliable data.

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