Living Polymerization - Living Cationic Polymerization

Living Cationic Polymerization

Monomers for living cationic polymerization are electron-rich alkenes such as vinyl ethers, isobutylene, styrene, and N-vinylcarbazole. The initiators are binary systems consisting of a electrophile and a Lewis acid. The method was developed around 1980 with contributions from Higashimura, Sawamoto and Kennedy.

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