Lithium Carbonate - Properties

Properties

Lithium carbonate, like almost all other lithium compounds, is soluble in water. The isolation of lithium from aqueous extracts of its ores capitalizes on this poor solubility. Its apparent solubility increases tenfold under a mild pressure of carbon dioxide; this effect is due to the formation of the metastable bicarbonate:

Li2CO3 + CO2 + H2O → 2 LiHCO3

Lithium carbonate, and other carbonates of Group 1, do not decompose readily, unlike other carbonates. Li2CO3 decomposes at temperatures greater than 1,300 °C (1,570 K).

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