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- Bobby Wadkins – professional golfer
- Lanny Wadkins – professional golfer
- Amina Wadud – controversial female Islamic VCU professor who led over 100 Muslims in prayer in New York on March 18, 2005
- Billy Wagner (born 1971) – retired MLB pitcher, played primarily for the Houston Astros and New York Mets
- Richard Wagoner – President of General Motors
- Maggie L. Walker – first woman to found a bank in the United States
- Travis Wall (born 1971) – reality TV star from So You Think You Can Dance: Season 2
- Ben Wallace – NBA basketball player
- Randall Wallace – writer, director, Braveheart, Pearl Harbor, We Were Soldiers
- Dylan Walsh § – actor, Nip/Tuck, Brooklyn South, Gabriel's Fire
- Booker T. Washington (1856–1915) – educator, activist, founder of Tuskegee Institute
- George Washington (1732–1799) – 1st President of the United States, commander-in-chief of Continental Army in the American Revolutionary War
- Kelley Washington (born 1979) – wide receiver for the Baltimore Ravens
- Benjamin Watson (born 1980) – tight end for the Cleveland Browns
- Haley Webb – actress
- Paul Wellstone § (1944–2002) – member of the United States Senate from Minnesota
- Suzanne Whang – TV host, actress, House Hunters, Las Vegas
- Jason White – NASCAR driver
- Tom Wiggin § (born 1955) – actor, Kirk Anderson on As the World Turns and Joe Foster on Texas
- L. Douglas Wilder (born 1931) – first elected African American governor of a U.S. state (Governor of Virginia, 1990–1994) and former Richmond City Mayor
- Jenny Wiley § (1760–1831) – pioneer, Native American captive
- Keller Williams (born 1970) – musician
- Kiely Williams – member of 3LW and The Cheetah Girls, actress "The House Bunny"
- Monty Williams – former NBA player and current head coach for the New Orleans Hornets
- Pharrell Williams (born 1973) – musician and music producer, one-half of The Neptunes
- Reggie Williams (born 1986) – player for the Charlotte Bobcats
- Steven Williams § (born 1949) – actor, 21 Jump Street, L.A. Heat, Linc's
- Carl Willis (born 1960) – pitching coach for the Seattle Mariners
- Curtis Wilkerson (born 1961) – MLB Player who played for the Texas Rangers, Chicago Cubs, Pittsburgh Pirates and Kansas City Royals.
- Casey Wilson (born 1980) – actress, comedienne, Happy Endings, Saturday Night Live
- David Wilson (born 1991) – running back for the New York Giants
- Patrick Wilson (born 1973) – actor, Nite Owl II in Watchmen
- Woodrow Wilson (1856–1924) – 28th President of the United States
- Stan Winston – film special effects designer
- Tom Wolfe (born 1931) – journalist and novelist and father of the "New Journalism"
- Carter G. Woodson (1875–1950) – African-American historian, author, founder of the Association for the Study of African American Life and History
- Damien Woody (born 1977) – retired offensive lineman for the New York Jets
- David Wright (born 1982) – MLB 3rd baseman, currently playing for the New York Mets
- George Wythe (1726–1806) Hampton; first professor of law in an American college, the College of William and Mary
Read more about this topic: List Of People From Virginia