B
- Spencer Bachus, representative from Alabama's 6th congressional district since 1993 (Vestavia Hills)
- Mary Badham, actress (Birmingham)
- Hank Ballard, singer (Bessemer)
- Tallulah Bankhead, actress (Jasper)
- Charles Barkley, basketball player (Leeds)
- Reggie Barlow, NFL wide receiver, college football coach (Montgomery)
- Mark Barron, NFL player- Tampa Bay Buccaneers (Mobile)
- Cynthia Bathurst, animal activist, founder of Safe Humane Chicago and the Court Case Dog Program
- Bill Baxley, former Lieutenant Governor of Alabama (Dothan)
- Lucy Baxley, lieutenant governor (2003-2007) (Vestavia Hills)
- Paul Bearer, WWE manager and wrestling promoter (Mobile)
- Jere Beasley, born Tyler, Texas, lieutenant governor (1971-1979) (Clayton)
- Scott Beason, Alabama state senator since 2006 (Hartselle)
- Barry Beckett, studio musician, guitarist, composer, record producer, original member of Muscle Shoals Rhythm Section (Muscle Shoals)
- Regina Benjamin, Surgeon General of the United States (Mobile)
- Earl Bennett, NFL wide receiver (Birmingham)
- Amber Benson, actress (Birmingham)
- Eric Bledsoe, basketball player (Birmingham)
- Bo Bice, "American Idol" contestant (Helena)
- Michael Biehn, actor (Anniston)
- James Gillespie Birney (1792–1857), planter, attorney, abolitionist (Huntsville)
- Sanford Bishop, U.S. representative from Georgia's 2nd congressional district (Mobile)
- Hugo Black; U.S. senator, United States Supreme Court justice (Harlan)
- Lucas Black, actor (Speake)
- Thomas Edwin Blanton, Jr., white supremacist and co-conspirator in the 16th Street Baptist Church bombing (Birmingham)
- Eric Bledsoe, NBA player- Los Angeles Clippers (Birmingham)
- Winton Blount, businessman, U.S. postmaster general from 1969-1972 (Union Springs)
- Michael Boley, NFL linebacker (Gadsden)
- Jo Bonner, representative from Alabama's 1st congressional district since 2003 (Mobile)
- Neil Bonnett, NASCAR driver (Hueytown)
- Young Boozer, current state treasurer (Montgomery)
- Albert Boutwell, lieutenant governor (1959-1963), mayor of Birmingham (1963-1967) (Birmingham)
- Bobby Bowden, college footbal coach (Birmingham)
- Rich Boy, rap artist (Mobile)
- Frank W. Boykin, former U.S. representative (Bladon Springs)
- Robert Bradley's Blackwater Surprise, music group (Evergreen)
- Rick Bragg, Pulitzer Prize-winning author (Possum Trot)
- Jeff Briggs, businessman, video game pioneer (Florence)
- Wernher von Braun; engineer, physicist (Huntsville) born Wirsitz, Province of Posen, Poland (then part of German Empire)
- Albert P. Brewer, governor 1968 to 1971 (Birmingham)
- Bobby Bright, mayor of Montgomery (1999-2009), representative from Alabama's 2nd congressional district (2009-2011) (Montgomery)
- David G. Bronner, CEO for Retirement Systems of Alabama (Montgomery) born Cresco, Iowa
- Mo Brooks, representative from Alabama's 5th congressional district since 2011 (Huntsville)
- Janice Rogers Brown, U.S. Court of Appeals judge (Luverne)
- Jerry Dolyn Brown; folk artist, traditional potter (Hamilton)
- Johnny Mack Brown; college football star- University of Alabama football, actor (Dothan)
- Matthew Brown; comedian -YouTube
- Roger Brown (artist), American artist who was a member of the Chicago Imagists,(Hamilton)
- Paul "Bear" Bryant, former head football coach - University of Alabama football, born in Camden, Arkansas (Tuscaloosa)
- John Hall Buchanan, Jr., representative from Alabama's 6th congressional district (1965-1981) (Birmingham and thereafter Bethesda, Maryland)
- Jimmy Buffett, singer/songwriter (Mobile), born Pascagoula, Mississippi
- Edward M. Burgess, American Chemist (Birmingham), Inventor of the Burgess reagent
- Edward A. Burkhalter; Admiral-United States Navy; Chief of Naval Intelligence; Chief of Staff, Defense Intelligence Agency; (Roanoke)
- Brett Butler, actress (Montgomery)
- Keith Butler, NFL coach- Pittsburgh Steelers (Anniston)
- Pat Buttram, actor (Addison)
- Larry Byrom, rock music guitarist- Steppenwolf (Huntsville)
Read more about this topic: List Of People From Alabama
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