Key
| Season | Each year is linked to an article about that particular Diamondbacks season. |
| W | Win |
| L | Loss |
| ND (W) | No decision by starting pitcher; Diamondbacks won game |
| ND (L) | No decision by starting pitcher; Diamondbacks lost game |
| Pitcher | Number of appearances as Opening Day starter with the Diamondbacks |
| * | Advanced to the postseason |
| ** | Won National League Championship Series |
| † | Won World Series |
Read more about this topic: List Of Arizona Diamondbacks Opening Day Starting Pitchers
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