Lanthanide Trifluoromethanesulfonates - Recent Developments

Recent Developments

Researchers are continually finding new applications where it can replace other less efficient, more toxic Lewis acids. Recently it has been tested in curing epoxies and other polymerisation reactions, and in polysaccharide synthesis. It has also been trialled in green solvents other than water, such as ionic liquids and supercritical carbon dioxide. To enhance recovery, researchers have developed La(OTf)3 catalysts stabilised by ion exchange resin or polymer backbones, which can be separated by ultrafiltration. Solvent-free systems are also possible with solid-supported catalysts.

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