In 1933 an aging Samiter found himself in dispute with the FC Barcelona management and he was dropped from the first team. Real Madrid, then known as Madrid CF, were quick to take advantage of the situation. Samitier was reunited with both his friend Ricardo Zamora and then Francisco Bru. Although his career with the Madrid club was short, he did help them win a La Liga title in 1932-33 and the Copa de España in 1934.
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