Jeremias Benjamin Richter - Law of Definite Proportions (stoichiometry)

Law of Definite Proportions (stoichiometry)

Evidence for the existence of atoms was the law of definite proportions proposed by him in 1792. Richter found that the ratio by weight of the compounds consumed in a chemical reaction was always the same. It took 615 parts by weight of magnesia (MgO), for example, to neutralize 1000 parts by weight of sulfuric acid. A few years later, when Joseph Proust reported his work on the constant composition of chemical compounds, the time was ripe for the reinvention of an atomic theory. The law of definite proportions and constant composition do not prove that atoms exist, but they are difficult to explain without assuming that chemical compounds are formed when atoms combine in constant proportions.

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