Isotopes of Oxygen - Radioisotopes

Radioisotopes

Fourteen radioisotopes have been characterized, with the most stable being 15O with a half-life of 122.24 s and 14O with a half-life of 70.606 s. All of the remaining radioactive isotopes have half-lives that are less than 27 s and the majority of these have half-lives that are less than 83 milliseconds (ms). For example, 24O has a half-life of 61 ms. The most common decay mode for isotopes lighter than the stable isotopes is β+ decay (to nitrogen) and the most common mode after is β- decay (to fluorine).

An atomic mass of 16 was assigned to oxygen prior to the definition of the unified atomic mass unit based upon 12C. Since physicists referred to 16O only, while chemists meant the naturally-abundant mixture of isotopes, this led to slightly different mass scales between the two disciplines.

The isotopic composition of oxygen atoms in the Earth's atmosphere is 99.759% 16O, 0.037% 17O and 0.204% 18O. Because water molecules containing the lighter isotope are slightly more likely to evaporate and fall as precipitation, fresh water and polar ice on earth contains slightly less (0.1981%) of the heavy isotope 18O than air (0.204%) or seawater (0.1995%). This disparity allows analysis of temperature patterns via historic ice cores.

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