Introduction To Quantum Mechanics - Wave-particle Duality

Wave-particle Duality

In 1924, Louis de Broglie proposed the idea that just as light has both wave-like and particle-like properties, matter also has wave-like properties.
The wavelength, λ, associated with a particle is related to its momentum, p through the Planck constant h :

The relationship, called the de Broglie hypothesis, holds for all types of matter. Thus all matter exhibits properties of both particles and waves.

Three years later, the wave-like nature of electrons was demonstrated by showing that a beam of electrons could exhibit diffraction, just like a beam of light. At the University of Aberdeen, George Thomson passed a beam of electrons through a thin metal film and observed the predicted diffraction patterns. At Bell Labs, Davisson and Germer guided their beam through a crystalline grid. Similar wave-like phenomena were later shown for atoms and even small molecules. De Broglie was awarded the Nobel Prize for Physics in 1929 for his hypothesis; Thomson and Davisson shared the Nobel Prize for Physics in 1937 for their experimental work.

The concept of wave-particle duality says that neither the classical concept of "particle" nor of "wave" can fully describe the behavior of quantum-scale objects, either photons or matter. Indeed, astrophysicist A.S. Eddington proposed in 1927 that "We can scarcely describe such an entity as a wave or as a particle; perhaps as a compromise we had better call it a 'wavicle' ". (This term was later popularised by mathematician Banesh Hoffmann.) Wave-particle duality is an example of the principle of complementarity in quantum physics. An elegant example of wave-particle duality, the double slit experiment, is discussed in the section below.

De Broglie's treatment of quantum events served as a jumping off point for Schrödinger when he set about to construct a wave equation to describe quantum theoretical events.

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