Physical Origin
Ideality of solutions is analogous to ideality for gases, with the important difference that intermolecular interactions in liquids are strong and can not simply be neglected as they can for ideal gases. Instead we assume that the mean strength of the interactions are the same between all the molecules of the solution.
More formally, for a mix of molecules of A and B, the interactions between unlike neighbors (UAB) and like neighbors UAA and UBB must be of the same average strength i.e. 2 UAB = UAA + UBB and the longer-range interactions must be nil (or at least indistinguishable). If the molecular forces are the same between AA, AB and BB, i.e. UAB = UAA = UBB, then the solution is automatically ideal.
If the molecules are almost identical chemically, e.g. 1-butanol and 2-butanol, then the solution will be almost ideal. Since the interaction energies between A and B are almost equal, it follows that there is a very small overall energy (enthalpy) change when the substances are mixed. The more dissimilar the nature of A and B, the more strongly the solution is expected to deviate from ideality.
Read more about this topic: Ideal Solution
Famous quotes containing the words physical and/or origin:
“Toddlerhood resembles adolescence because of the rapidity of physical growth and because of the impulse to break loose of parental boundaries. At both ages, the struggle for independence exists hand in hand with the often hidden wish to be contained and protected while striving to move forward in the world. How parents and toddlers negotiate their differences sets the stage for their ability to remain partners during childhood and through the rebellions of the teenage years.”
—Alicia F. Lieberman (20th century)
“In the woods in a winter afternoon one will see as readily the origin of the stained glass window, with which Gothic cathedrals are adorned, in the colors of the western sky seen through the bare and crossing branches of the forest.”
—Ralph Waldo Emerson (1803–1882)