Criticism
In 2011, Herbert Mayr et al. from Ludwig Maximilian University of Munich (LMU) published a critical review in Angewandte Chemie. Consecutive analysis of various types of ambident organic system reveals that an older approach based on thermodynamic/kinetic control describes reactivity of organic compounds perfectly, while the HSAB principle actually fails and should be abandoned in the rationalization of ambident reactivity of organic compounds.
Read more about this topic: HSAB Theory
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