In molecular vibrational spectroscopy, a hot band is a band centred on a hot transition, which is a transition between two excited vibrational states, i.e. neither is the overall ground state. In infrared or Raman spectroscopy, hot bands refer to those transitions for a particular vibrational mode which arise from a state containing thermal population of another vibrational mode. For example, for a molecule with 3 normal modes, and, the transition ←, would be a hot band, since the initial state has one quantum of excitation in the mode. Hot bands are distinct from combination bands, which involve simultaneous excitation of multiple normal modes with a single photon, and overtones, which are transitions that involve changing the vibrational quantum number for a normal mode by more than 1.
Read more about Hot Band: Vibrational Hot Bands, Combination Bands
Famous quotes containing the words hot and/or band:
“Away went the messenger’s bicycle,
His serpent’s track went up the hill forever.
And all the time she stood there hot as fever
And cold as any icicle.”
—John Crowe Ransom (1888–1974)
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—Fran Lebowitz (b. 1950)