Hiyama Coupling

Hiyama Coupling

The Hiyama-coupling is a palladium-catalyzed cross-coupling reaction of organosilanes with organic halides used in organic chemistry to form carbon-carbon bonds (C-C bonds). This reaction was discovered in 1988 by Tamejiro Hiyama and Yasuo Hatanaka as a method to form carbon-carbon bonds synthetically with chemo- and regioselectivity. This reaction has been applied to the synthesis of natural products such as Papulacadin D, an anti-fungal agent.

Read more about Hiyama Coupling:  Reaction History, Mechanism, Variations

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