Magnetism
Hematite is an antiferromagnetic material below the Morin transition at 250 K, and a canted antiferromagnet or weakly ferromagnetic above the Morin transition and below its Néel temperature at 948 K, above which it is paramagnetic.
The magnetic structure of a-hematite was the subject of considerable discussion and debate in the 1950s because it appeared to be ferromagnetic with a Curie temperature of around 1000 K, but with an extremely tiny moment (0.002 µB). Adding to the surprise was a transition with a decrease in temperature at around 260 K to a phase with no net magnetic moment. It was shown that the system is essentially antiferromagnetic, but that the low symmetry of the cation sites allows spin–orbit coupling to cause canting of the moments when they are in the plane perpendicular to the c axis. The disappearance of the moment with a decrease in temperature at 260 K is caused by a change in the anisotropy which causes the moments to align along the c axis. In this configuration, spin canting does not reduce the energy. The magnetic properties of bulk hematite differ from their nanoscale counterparts. For example, Morin transition temperature of hematite decreases with decrease in the particle size. The suppression of this transition have also been observed in some of the hematite nanoparticles and the presence of impurities, water molecule and defects in the crystals were attributed to the absence of Morin transition. Hematite is part of a complex solid solution oxyhydroxide system having various contents of water, hydroxyl groups and vacancy substitutions that affect the mineral's magnetic and crystal chemical properties. Two other end-members are referred to as protohematite and hydrohematite.
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