HAZMAT Class 5 Oxidizing Agents and Organic Peroxides - Packing Groups

Packing Groups

Class 5 Packing Groups
Group Division Phase Details
Group I 5.1 Solid Any material which, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3:2 potassium bromate/cellulose mixture.
Group II 5.1 Solid Any material which, in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met.
Group III 5.1 Solid Any material which, in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met.
Group I 5.1 Liquid
  1. Any material which spontaneously ignites when mixed with cellulose in a 1:1 ratio; or
  2. Any material which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50 percent)/cellulose mixture.
Group II 5.1 Liquid Any material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 aqueous sodium chlorate solution(40 percent)/cellulose mixture and the criteria for Group I are not met.
Group III 5.1 Liquid Any material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65 percent)/cellulose mixture and the criteria for Packing Group I and II are not met.
Group II 5.2 All All Division 5.2 materials are assigned to Packing Group II in Column 5 of the 49 CFR 172.101 Table.

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