Definition
Grand potential is defined by
where U is the internal energy, T is the temperature of the system, S is the entropy, μ is the chemical potential, and N is the number of particles in the system.
The change in the grand potential is given by
where P is pressure and V is volume, using the fundamental thermodynamic relation (combined first and second thermodynamic laws);
When the system is in thermodynamic equilibrium, ΦG is a minimum. This can be seen by considering that dΦG is zero if the volume is fixed and the temperature and chemical potential have stopped evolving.
Read more about this topic: Grand Potential
Famous quotes containing the word definition:
“The very definition of the real becomes: that of which it is possible to give an equivalent reproduction.... The real is not only what can be reproduced, but that which is always already reproduced. The hyperreal.”
—Jean Baudrillard (b. 1929)
“I’m beginning to think that the proper definition of “Man” is “an animal that writes letters.””
—Lewis Carroll [Charles Lutwidge Dodgson] (1832–1898)
“Mothers often are too easily intimidated by their children’s negative reactions...When the child cries or is unhappy, the mother reads this as meaning that she is a failure. This is why it is so important for a mother to know...that the process of growing up involves by definition things that her child is not going to like. Her job is not to create a bed of roses, but to help him learn how to pick his way through the thorns.”
—Elaine Heffner (20th century)