Examples
One of the simplest examples is complexification, which is extension of scalars from the real numbers to the complex numbers. More generally, given any field extension K < L, one can extend scalars from K to L. In the language of fields, a module over a field is called a vector space, and thus extension of scalars converts a vector space over K to a vector space over L. This can also be done for division algebras, as is done in quaternionification (extension from the reals to the quaternions).
More generally, given a homomorphism from a field or commutative ring R to a ring S, the ring S can be thought of as an associative algebra over R, and thus when one extends scalars on an R-module, the resulting module can be thought of alternatively as an S-module, or as an R-module with an algebra representation of S (as an R-algebra). For example, the result of complexifying a real vector space (R = R, S = C) can be interpreted either as a complex vector space (S-module) or as a real vector space with a linear complex structure (algebra representation of S as an R-module).
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