Dynamic nuclear polarization (DNP) results from transferring spin polarization from electrons to nuclei, thereby aligning the nuclear spins to the extent that electron spins are aligned. Note that the alignment of electron spins at a given magnetic field and temperature is described by the Boltzmann distribution under the thermal equilibrium (see figure). It is also possible that those electrons are aligned to a higher degree of order by other preparations of electron spin order such as: chemical reactions (leading to Chemical-Induced DNP, CIDNP), optical pumping and spin injection. DNP is considered one of several techniques for hyperpolarization.
When electron spin polarization deviates from its thermal equilibrium value, polarization transfers between electrons and nuclei can occur spontaneously through electron-nuclear cross relaxation and/or spin-state mixing among electrons and nuclei. For example, the polarization transfer is spontaneous after a homolysis chemical reaction. On the other hand, when the electron spin system is in a thermal equilibrium, the polarization transfer requires continuous microwave irradiation at a frequency close to the corresponding electron paramagnetic resonance (EPR) frequency. In particular, mechanisms for the microwave-driven DNP processes are categorized into the Overhauser effect (OE), the solid-effect (SE), the cross-effect (CE) and thermal-mixing (TM).
The first DNP experiments were performed in the early 1950s at low magnetic fields, but until recently the technique was of limited applicability for high-frequency, high-field NMR spectroscopy, because of the lack of microwave (terahertz) sources operating at the appropriate frequency. Today such sources are available as turn-key instruments, making DNP a valuable and indispensable method especially in the field of structure determination by high-resolution solid-state NMR spectroscopy
Famous quotes containing the words dynamic and/or nuclear:
“Knowledge about life is one thing; effective occupation of a place in life, with its dynamic currents passing through your being, is another.”
—William James (1842–1910)
“Could it not be that just at the moment masculinity has brought us to the brink of nuclear destruction or ecological suicide, women are beginning to rise in response to the Mother’s call to save her planet and create instead the next stage of evolution? Can our revolution mean anything else than the reversion of social and economic control to Her representatives among Womankind, and the resumption of Her worship on the face of the Earth? Do we dare demand less?”
—Jane Alpert (b. 1947)