Quantum Mechanical Application
In quantum mechanical and quantum chemical computations matrix diagonalization is one of the most frequently applied numerical processes. The basic reason is that the time-independent Schrödinger equation is an eigenvalue equation, albeit in most of the physical situations on an infinite dimensional space (a Hilbert space). A very common approximation is to truncate Hilbert space to finite dimension, after which the Schrödinger equation can be formulated as an eigenvalue problem of a real symmetric, or complex Hermitian, matrix. Formally this approximation is founded on the variational principle, valid for Hamiltonians that are bounded from below. But also first-order perturbation theory for degenerate states leads to a matrix eigenvalue problem.
Read more about this topic: Diagonalizable Matrix
Famous quotes containing the words quantum, mechanical and/or application:
“The receipt to make a speaker, and an applauded one too, is short and easy.—Take of common sense quantum sufficit, add a little application to the rules and orders of the House, throw obvious thoughts in a new light, and make up the whole with a large quantity of purity, correctness, and elegancy of style.”
—Philip Dormer Stanhope, 4th Earl Chesterfield (1694–1773)
“Industry has operated against the artisan in favor of the idler, and also in favor of capital and against labor. Any mechanical invention whatsoever has been more harmful to humanity than a century of war.”
—Rémy De Gourmont (1858–1915)
“The best political economy is the care and culture of men; for, in these crises, all are ruined except such as are proper individuals, capable of thought, and of new choice and the application of their talent to new labor.”
—Ralph Waldo Emerson (1803–1882)