Cyclic Voltammetry - Variations

Variations

In some experiments an electroactive species is fixed to the surface of the electrode, for instance in microparticle voltammetry.

Potentiodynamic techniques also exist that add low-amplitude ac perturbation to a potential ramp and measure variable response in a single frequency (ac voltammetry) or in many frequencies simultaneously (potentiodynamic electrochemical impedance spectroscopy). The response in alternating current is two-dimensional – it is characterised by amplitude and phase. The amplitude and phase depend differently on frequency for constituents of ac response attributed to different processes (charge transfer, diffusion, double layer charging, etc.). Frequency response analysis enables simultaneous monitoring of the various processes that contribute to the potentiodynamic ac response of electrochemical system.

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