'The' Homotopy Category
The homotopy category of CW complexes is, in the opinion of some experts, the best if not the only candidate for the homotopy category (for technical reasons the version for pointed spaces is actually used). Auxiliary constructions that yield spaces that are not CW complexes must be used on occasion. One basic result is that the representable functors on the homotopy category have a simple characterisation (the Brown representability theorem).
Read more about this topic: CW Complex
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