Collision Theory - Rate Constant

Rate Constant

The rate constant for a bimolecular gas phase reaction, as predicted by collision theory is:

.

where:

  • Z is the .
  • is the steric factor.
  • Ea is the activation energy of the reaction.
  • T is the temperature.
  • R is gas constant.

The collision frequency is:

where:

  • NA is the Avogadro constant
  • σAB is the reaction cross section
  • kB is Boltzmann's constant
  • μAB is the reduced mass of the reactants.

Read more about this topic:  Collision Theory

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