Formation
The amount of water that can exist as vapor in a given volume increases with the temperature. When the amount of water vapor is in equilibrium above a flat surface of water the level of vapor pressure is called saturation and the relative humidity is 100%. At this equilibrium there are equal numbers of molecules evaporating from the water as there are condensing back into the water. If the relative humidity becomes greater than 100%, it is called supersaturated. Supersaturation occurs in the absence of condensation nuclei, for example the flat surface of water.
Since the saturation vapor pressure is proportional to temperature, cold air has a lower saturation point than warm air. The difference between these values is the basis for the formation of clouds. When saturated air cools, it can no longer contain the same amount of water vapor. If the conditions are right, the excess water will condense out of the air until the lower saturation point is reached. Another possibility is that the water stays in vapor form, even though it is beyond the saturation point, resulting in supersaturation.
Read more about this topic: Cloud Physics
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