Relation To The Ideal Gas Law
French physicist Émile Clapeyron combined Charles's law with Boyle's law in 1834 to produce a single statement which would become known as the ideal gas law. Claypeyron's original statement was:
where t is the Celsius temperature; and p0, V0 and t0 are the pressure, volume and temperature of a sample of gas under some standard state. The figure of 267 came directly from Gay-Lussac's work: the modern figure would be 273.15. For any given sample of gas, p0V0⁄267+t0 is a constant (Clapeyron denoted this constant R, and it is closely related to the modern gas constant); if the pressure is also constant, the equation simplifies to
as required.
The modern statement of the ideal gas law is:
where n is the amount of substance of the gas sample; and R is the gas constant. The amount of substance is constant for any given gas sample so, at constant pressure, the equation rearranges to:
where nR⁄p is the constant of proportionality.
An ideal gas is defined as a gas which obeys the ideal gas law, so Charles' law is only expected to be followed exactly by ideal gases. Nevertheless, it is a good approximation to the behaviour of real gases at relatively high temperatures and relatively low pressures.
Read more about this topic: Charles's Law
Famous quotes containing the words relation to the, relation to, relation, ideal, gas and/or law:
“Concord is just as idiotic as ever in relation to the spirits and their knockings. Most people here believe in a spiritual world ... in spirits which the very bullfrogs in our meadows would blackball. Their evil genius is seeing how low it can degrade them. The hooting of owls, the croaking of frogs, is celestial wisdom in comparison.”
—Henry David Thoreau (1817–1862)
“The adolescent does not develop her identity and individuality by moving outside her family. She is not triggered by some magic unconscious dynamic whereby she rejects her family in favour of her peers or of a larger society.... She continues to develop in relation to her parents. Her mother continues to have more influence over her than either her father or her friends.”
—Terri Apter (20th century)
“There is undoubtedly something religious about it: everyone believes that they are special, that they are chosen, that they have a special relation with fate. Here is the test: you turn over card after card to see in which way that is true. If you can defy the odds, you may be saved. And when you are cleaned out, the last penny gone, you are enlightened at last, free perhaps, exhilarated like an ascetic by the falling away of the material world.”
—Andrei Codrescu (b. 1947)
“Cassoulet, that best of bean feasts, is everyday fare for a peasant but ambrosia for a gastronome, though its ideal consumer is a 300-pound blocking back who has been splitting firewood nonstop for the last twelve hours on a subzero day in Manitoba.”
—Julia Child (b. 1912)
“... when I awake in the middle of the night, since I knew not where I was, I did not even know at first who I was; I only had in the first simplicity the feeling of existing as it must quiver in an animal.... I spent one second above the centuries of civilization, and the confused glimpse of the gas lamps, then of the shirts with turned-down collars, recomposed, little by little, the original lines of my self.”
—Marcel Proust (1871–1922)
“These, having not the law, are a law unto themselves.”
—Bible: New Testament St. Paul, in Romans, 2:14.