Relation To The Ideal Gas Law
French physicist Émile Clapeyron combined Charles's law with Boyle's law in 1834 to produce a single statement which would become known as the ideal gas law. Claypeyron's original statement was:
where t is the Celsius temperature; and p0, V0 and t0 are the pressure, volume and temperature of a sample of gas under some standard state. The figure of 267 came directly from Gay-Lussac's work: the modern figure would be 273.15. For any given sample of gas, p0V0⁄267+t0 is a constant (Clapeyron denoted this constant R, and it is closely related to the modern gas constant); if the pressure is also constant, the equation simplifies to
as required.
The modern statement of the ideal gas law is:
where n is the amount of substance of the gas sample; and R is the gas constant. The amount of substance is constant for any given gas sample so, at constant pressure, the equation rearranges to:
where nR⁄p is the constant of proportionality.
An ideal gas is defined as a gas which obeys the ideal gas law, so Charles' law is only expected to be followed exactly by ideal gases. Nevertheless, it is a good approximation to the behaviour of real gases at relatively high temperatures and relatively low pressures.
Read more about this topic: Charles's Law
Famous quotes containing the words relation to, relation, ideal, gas and/or law:
“Only in a house where one has learnt to be lonely does one have this solicitude for things. One’s relation to them, the daily seeing or touching, begins to become love, and to lay one open to pain.”
—Elizabeth Bowen (1899–1973)
“Among the most valuable but least appreciated experiences parenthood can provide are the opportunities it offers for exploring, reliving, and resolving one’s own childhood problems in the context of one’s relation to one’s child.”
—Bruno Bettelheim (20th century)
“The unique eludes us; yet we remain faithful to the ideal of it; and in spite of sense and of our merely abstract thinking, it becomes for us the most real thing in the actual world, although for us it is the elusive goal of an infinite quest.”
—Josiah Royce (1855–1916)
“one pale woman all alone,
The daylight kissing her wan hair,
Loitered beneath the gas lamps’ flare,
With lips of flame and heart of stone.”
—Oscar Wilde (1854–1900)
“The very existence of government at all, infers inequality. The citizen who is preferred to office becomes the superior to those who are not, so long as he is the repository of power, and the child inherits the wealth of the parent as a controlling law of society.”
—James Fenimore Cooper (1789–1851)