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- Ed Chapman (artist), British artist
- Eddie Chapman
- Eddie Chapman (1914–1997), British spy and double agent, aka Agent Zigzag
- Eddie Chapman (footballer) (1923–2002), English footballer and chairman
- Edmund Chapman (1695–1763), English cricketer
- Edward Chapman
- Edward Chapman (actor) (1901–1977), British comic actor
- Edward Chapman (politician) (1839–1906), British Conservative Party politician
- Ernest William Chapman (1894–1947), US-American mineralogist
- Edward John Chapman (1821–1904), English-Canadian mineralogist
- Edward Thomas Chapman (1920–2002), Welsh corporal and recipient of the Victoria Cross
- Edythe Chapman (1863–1948), American stage and silent film actress
- Ellen Chapman, American beauty queen
- Elizabeth Chapman, Children's author
- Emmett Chapman, British jazz musician best known as the inventor of the musical instrument Chapman Stick
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