Carbon Disulfide - Occurrence and Manufacture

Occurrence and Manufacture

Small amounts of carbon disulfide are released by volcanic eruptions and marshes. CS2 once was manufactured by combining carbon (or coke) and sulfur at high temperatures. A lower temperature reaction, requiring only 600 °C utilizes natural gas as the carbon source in the presence of silica gel or alumina catalysts:

2CH4 + S8 → 2CS2 + 4H2S

The reaction is analogous to the combustion of methane. Although it is isoelectronic with carbon dioxide, CS2 is highly flammable:

CS2 + 3O2 → CO2 + 2SO2

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