Calcium Oxalate - Occurrence

Occurrence

Quantities of calcium oxalate are found in many tropical house plants. Calcium oxalate is a poisonous substance that can produce sores and numbing on ingestion and could even be fatal. The poisonous plant dumb cane (Dieffenbachia) contains the substance and on ingestion can prevent speech and be suffocating. It is also found in rhubarb (in large quantities in the leaves) and in species of Oxalis, Araceae, taro, kiwifruit, tea leaves, agaves, and Alocasia and in spinach in varying amounts. Insoluble calcium oxalate crystals are found in plant stems, roots, and leaves and produced in idioblasts. Kidney stone sufferers should not eat plants high in oxalates.

Calcium oxalate, as 'beerstone', is a brownish precipitate that tends to accumulate within vats, barrels and other containers used in the brewing of beer. If not completely removed in a cleaning process, beerstone will leave an unsanitary surface that can harbour microorganisms. Beerstone is composed of calcium and magnesium salts and various organic compounds left over from the brewing process; it promotes the growth of unwanted microorganisms that can adversely affect or even ruin the flavor of a batch of beer.

Calcium oxalate crystals in the urine are the most common constituent of human kidney stones, and calcium oxalate crystal formation is also one of the toxic effects of ethylene glycol poisoning.

Hydrated forms of the compound occur naturally as three mineral species: whewellite (monohydrate, known from some coal beds), weddellite (dihydrate) and a very rare trihydrate called caoxite.

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