Aerogels
Skylights, solariums and other special applications may use aerogels, a high-performance, low-density material. Silica aerogel has the lowest thermal conductivity of any known substance (short of a vacuum), and carbon aerogel absorbs infrared radiation (i.e., heat from sun rays) while still allowing daylight to enter. The combination of silica and carbon aerogel gives the best insulating properties of any known material, approximately twice the insulative protection of the next best insulative material, closed-cell foam.
Read more about this topic: Building Insulation Materials