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General Arthur Wellesley, 1st Marquess of Wellington
- Right Center Column (General the Marquess of Wellington)
- 4th Division (Lieut-Gen. Lowry Cole) (7,300)
- Light Division (Maj-Gen. Charles Alten) (5,500)
- Cavalry
- Household Cavalry Brigade (Lieut-Col. Robert Hill) (900)
- Light Cavalry Brigade (Col. Colquhoun Grant) (1,600)
- Heavy Cavalry Brigade (Maj-Gen William Ponsonby) (1,200)
- Portuguese Cavalry Brigade (Brig-Gen. Benjamin D'Urban) (700)
- Artillery (Major Augustus Simon Frazer)
- Ross' troop RHA
- Gardiner's troop RHA
- Ramsay's troop RHA
- Sympher's battery KGL
- Right Column (Lieut-Gen. Rowland Hill)
- 2nd Division (Lieut-Gen. William Stewart) (10,800)
- Portuguese Division (Maj-Gen. Francisco Silveira, Count of Amarante) (5,300)
- Spanish Division (Maj-Gen. Pablo Morillo) (4,600)
- Cavalry
- Light Cavalry Brigade (Maj-Gen. Victor Alten) (1,000)
- Heavy Cavalry Brigade (Maj-Gen. Henry Fane) (800)
- Artillery (Maj. Joseph Carncross)
- Beane's troop RHA
- Maxwell's battery RA
- Tulloh's 2 Portuguese batteries
- Left Centre Column (Lieut-Gen. George Ramsay, 9th Earl of Dalhousie)
- 3rd Division (Lieut-Gen. Thomas Picton) (7,500)
- 1st Brigade (Maj-Gen. Thomas Brisbane)
- 2nd Brigade (Maj-Gen. Charles Colville)
- Power's Portuguese Brigade (Maj-Gen. Manley Power)
- 7th Division (Lieut-Gen. the Earl of Dalhousie) (7,300)
- Artillery (Maj. Richard Buckner)
- Cairnes' Battery RA
- Douglas' Battery RA
- Left Column (Lieut-Gen. Thomas Graham)
- 1st Division (Maj-Gen. Kenneth Howard) (4,900)
- 5th Division (Maj-Gen. John Oswald) (6,700)
- Portuguese Independent Brigade (Maj-Gen. Denis Pack) (2,300)
- Portuguese Independent Brigade (Maj-Gen. Thomas Bradford) (2,400)
- Spanish Division (Col. Francisco de Longa) (3,100)
- Cavalry
- Light Cavalry Brigade (Maj-Gen. George Anson) (800)
- Heavy Cavalry Brigade (Maj-Gen. George Bock) (600)
- Artillery
- Dubordieu's battery RA
- Lawson's battery RA
- Reserve Artillery (Lieut-Col. Julius Hartmann)
- Webber-Smith's troop RHA
- Parker's battery RA
- Arriaga's Portuguese battery
Distributed among the four columns, the Allied army had 4,300 gunners
plus 900 engineers, wagoneers and support troops.
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King Joseph Bonaparte
Marshal Jean Baptiste Jourdan
- Army of the South (Maj-Gen. Honoré Gazan)
- 1st Division (Maj-Gen. Jean François Leval) (4,700)
- 3rd Division (Maj-Gen. Eugene-Casimir Villatte) (5,700)
- 4th Division (Maj-Gen. Nicolas François Conroux) (6,400)
- 6th Division (Maj-Gen. Augustin Darricau) (5,700)
- Independent Brigade (Brig-Gen. Jean-Pierre Maransin) (2,900)
- 1st Cavalry Division (Maj-Gen. Pierre Benoit Soult) (1,500)
- 2nd Cavalry Division (Maj-Gen. Jacques Delaistre de Tilly) (1,900)
- 3rd Cavalry Division (Maj-Gen. Alexandre Digeon) (1,700)
- Artillery, Engineers, support troops (2,400)
- Army of the Centre (Maj-Gen. Jean-Baptiste Drouet D'Erlon)
- 1st Division (Maj-Gen. Jean Darmagnac) (4,500)
- 2nd Division (Maj-Gen. Louis Cassagne) (5,200) on loan from Army of the South
- 1st Cavalry Division (Maj-Gen. Anne-François-Charles Trelliard) (1,000)
- 2nd Cavalry Division (Maj-Gen. Antoine Avy) (500)
- Artillery, Engineers, support troops (800)
- Army of Portugal (Maj-Gen. Honoré Reille)
- 4th Division (Maj-Gen. Jacques Sarrut) (4,800)
- 6th Division (Maj-Gen. Thomas Mignot de Lamartinière) (6,500)
- 1st Cavalry Division (Maj-Gen. Julien Mermet) (1,800)
- 2nd Cavalry Division (Maj-Gen. Pierre Boyer) (1,500)
- Artillery, Engineers and support troops (2,500)
- King Joseph's Spanish Army
- (French) Royal Guard (Maj-Gen. Guy) (2,300 infantry, 400 cavalry)
- (Spanish) Troops of the Line (Gen. Casapalacios) (2,100 infantry, 700 cavalry and 100 gunners)
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