History
Acetone peroxide was discovered in 1895 by Richard Wolffenstein. He was the first chemist to use inorganic acids as catalysts. He was also the first researcher to receive a patent for using the peroxide as an explosive compound. In 1900 Bayer and Villiger described in the same journal the first synthesis of the dimer and also described use of acids for the synthesis of both peroxides. Information about these procedures including the relative proportions of monomer, dimer, and trimer is also available in an article by Milas and Golubović. Other sources include crystal structure and 3d analysis in The Chemistry of Peroxides edited by Saul Patai (pp. 396–7), as well as the Textbook of Practical Organic Chemistry by Vogel.
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