Quarter Finals
- Note: Second leg between Vasco da Gama and Atlético Nacional was a replay in Santiago (Chile). The original match ended with a victory by 2-0 for Atlético Nacional, but it was annulled following a protest by Vasco da Gama complaining of pressure on the referee by local drug lords.
| Team 1 | Agg. | Team 2 | 1st leg | 2nd leg |
|---|---|---|---|---|
| Vasco da Gama | 0–1 | Atlético Nacional | 0–0 | 0–1 |
| Emelec | 0–1 | Barcelona | 0–0 | 0–1 |
| River Plate | 3–1 | Independiente | 2–0 | 1–1 |
| Olimpia | 6–4 | Universidad Católica | 2–0 | 4–4 |
Read more about this topic: 1990 Copa Libertadores
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