Theory
Data analysis requires the consideration of kinetics in addition to thermodynamics, due to the temporal component of voltammetry. Idealized theoretical electrochemical thermodynamic relationships such as the Nernst equation are modeled without a time component. While these models are insufficient alone to describe the dynamic aspects of voltammetry, models like the Tafel equation and Butler-Volmer equation lay the groundwork for the modified voltammetry relationships that relate theory to observed results.
Read more about this topic: Voltammetry
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