Structure
It has many polymorphic forms all based largely on octahedrally coordinated niobium atoms. The polymorphs are identified with a variety of prefixes. The form most commonly encountered is monoclinic H-Nb2O5 which has a complex structure, with a unit cell containing 28 niobium atoms and 70 oxygen, where 27 of the niobium atoms are octahedrally coordinated and one tetrahedrally. There is an uncharacterised solid hydrate, Nb2O5.nH2O, the so-called niobic acid (previously called columbic acid), which can be prepared by hydrolysis of a basic solution of niobium pentachloride or Nb2O5 dissolved in HF.
Read more about this topic: Niobium Pentoxide
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