Formal Approach
The formal basis for mean field theory is the Bogoliubov inequality. This inequality states that the free energy of a system with Hamiltonian
has the following upper bound:
where is the entropy and where the average is taken over the equilibrium ensemble of the reference system with Hamiltonian . In the special case that the reference Hamiltonian is that of a non-interacting system and can thus be written as
where is shorthand for the degrees of freedom of the individual components of our statistical system (atoms, spins and so forth). One can consider sharpening the upper bound by minimizing the right hand side of the inequality. The minimizing reference system is then the "best" approximation to the true system using non-correlated degrees of freedom, and is known as the mean field approximation.
For the most common case that the target Hamiltonian contains only pairwise interactions, i.e.,
where is the set of pairs that interact, the minimizing procedure can be carried out formally. Define as the generalized sum of the observable over the degrees of freedom of the single component (sum for discrete variables, integrals for continuous ones). The approximating free energy is given by
where is the probability to find the reference system in the state specified by the variables . This probability is given by the normalized Boltzmann factor
where is the partition function. Thus
In order to minimize we take the derivative with respect to the single degree-of-freedom probabilities using a Lagrange multiplier to ensure proper normalization. The end result is the set of self-consistency equations
where the mean field is given by
Read more about this topic: Mean Field Theory
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