The Asianet Film Award for Best Star Pair has been awarded since 2001.
| Year | Star pair | Film |
|---|---|---|
| 2012 | Nivin Pauly & Isha Talwar | Thattathin Marayathu |
| 2011 | Asif Ali & Mythili | Salt N' Pepper |
| 2010 | Kunchacko Boban & Archana Kavi | Mummy & Me |
| 2009 | Jayasurya & Roma | Utharaswayamvaram |
| 2008 | Jayasurya & Roma | Minnaminnikoottam, Shakespeare M.A. Malayalam |
| 2007 | Vinu Mohan & Bhama | Nivedyam |
| 2006 | Jeeva & Gopika | Keerthichakra |
| 2002 | Dileep & Kavya Madhavan | Meesa Madhavan |
| 2001 | Biju Menon & Samyuktha Varma | Meghamalhar |
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