Scope
IBX is also available as silica gel or polystyrene bound IBX. In many application IBX acid is replaced by Dess-Martin periodinane which is more soluble in common organic solvents. A sample reaction is an IBX oxidation used in the total synthesis of eicosanoid:
.
In 2001, K. C. Nicolaou and co-workers published a series of papers in the Journal of the American Chemical Society demonstrating, among other transformations, the use of IBX to oxidize benzylic carbons to conjugated aromatic carbonyl compounds.
Read more about this topic: 2-Iodoxybenzoic Acid
Famous quotes containing the word scope:
“The scope of modern government in what it can and ought to accomplish for its people has been widened far beyond the principles laid down by the old laissez faire school of political rights, and the widening has met popular approval.”
—William Howard Taft (18571930)
“In the works of man, everything is as poor as its author; vision is confined, means are limited, scope is restricted, movements are labored, and results are humdrum.”
—Joseph De Maistre (17531821)
“As the creative adult needs to toy with ideas, the child, to form his ideas, needs toysand plenty of leisure and scope to play with them as he likes, and not just the way adults think proper. This is why he must be given this freedom for his play to be successful and truly serve him well.”
—Bruno Bettelheim (20th century)