Preparation, Properties, and Related Compounds
It is prepared by thermal decomposition of VCl3, which leaves a residue of VCl2:
- 2 VCl3 → VCl2 + VCl4
VBr2 and VI2 are structurally and chemically similar to the dichloride. All have the d3 configuration, with a quartet ground state, akin to Cr(III).
Vanadium dichloride is a powerful reducing species, being able to reduce sulfoxides to sulfides, organic azides to amines, as well as reductively coupling some alkyl halides. VCl2 dissolves in water to give the hexaaquo ion 2+. Evaporation of such solutions produces crystals of Cl2.
Read more about this topic: Vanadium(II) Chloride
Famous quotes containing the words related and/or compounds:
“The near explains the far. The drop is a small ocean. A man is related to all nature. This perception of the worth of the vulgar is fruitful in discoveries. Goethe, in this very thing the most modern of the moderns, has shown us, as none ever did, the genius of the ancients.”
—Ralph Waldo Emerson (1803–1882)
“We can come up with a working definition of life, which is what we did for the Viking mission to Mars. We said we could think in terms of a large molecule made up of carbon compounds that can replicate, or make copies of itself, and metabolize food and energy. So that’s the thought: macrocolecule, metabolism, replication.”
—Cyril Ponnamperuma (b. 1923)