Change of Internal State of An Isolated System
If an isolated system is left long enough, it will reach a state of thermal equilibrium, in which its temperature will be uniform throughout, but not necessarily a state of thermodynamic equilibrium, if there is some structural barrier that can prevent some possible processes in the system from reaching equilibrium. An isolated system can change its temperature or its spatial distribution of temperature by changing the state of Longley, R.G. Van Name, Longmans, Green & Co., New York, 1928, volume 1, pages 55-353, particularly pages 144-150. A system prepared as a mixture of petrol vapour and air can be ignited by a spark and produce carbon dioxide and water; if this happens in an isolated system, it will increase the temperature of the system, and during the increase, the system is not in thermal equilibrium; but eventually the system will settle to a uniform temperature. In a system prepared as a block of ice floating in a bath of hot water, and then isolated, the ice can melt; during the melting, the system is not in thermal equilibrium; but eventually its temperature will become uniform. Such changes in isolated systems are irreversible in the sense that while such a change will occur spontanteously whenever the system is prepared in the same way, the reverse change will never occur spontanteously within the isolated system; this is a large part of the content of the second law of thermodynamics. Truly isolated systems hardly occur in nature, and nearly always are artificially prepared.
Read more about this topic: Thermal Equilibrium
Famous quotes containing the words change of, change, internal, state, isolated and/or system:
“When man has nothing but his will to assert—even his good-will—it is always bullying. Bolshevism is one sort of bullying, capitalism another: and liberty is a change of chains.”
—D.H. (David Herbert)
“... often in the heat of noonday, leaning on a hoe, looking across valleys at the mountains, so blue, so close, my only conscious thought was, “How can I ever get away from here? How can I get to where they have books, where I can be educated?” I worked hard, always waiting for something to happen to change things. There came a time when I knew I must make them happen; that no one would do anything about it for me. And I did.”
—Belinda Jelliffe (1892–1979)
“The burning of rebellious thoughts in the little breast, of internal hatred and opposition, could not long go on without slight whiffs of external smoke, such as mark the course of subterranean fire.”
—Harriet Beecher Stowe (1811–1896)
“There is one consolation in being sick; and that is the possibility that you may recover to a better state than you were ever in before.”
—Henry David Thoreau (1817–1862)
“Without the meditative background that is criticism, works become isolated gestures, ahistorical accidents, soon forgotten.”
—Milan Kundera (b. 1929)
“The individual protests against the world, but he doesn’t get beyond protest, he is just a single protester. When he wants to be more than that, he has to counter power with power, he has to oppose the system with another system.”
—Friedrich Dürrenmatt (1921–1990)