Change of Internal State of An Isolated System
If an isolated system is left long enough, it will reach a state of thermal equilibrium, in which its temperature will be uniform throughout, but not necessarily a state of thermodynamic equilibrium, if there is some structural barrier that can prevent some possible processes in the system from reaching equilibrium. An isolated system can change its temperature or its spatial distribution of temperature by changing the state of Longley, R.G. Van Name, Longmans, Green & Co., New York, 1928, volume 1, pages 55-353, particularly pages 144-150. A system prepared as a mixture of petrol vapour and air can be ignited by a spark and produce carbon dioxide and water; if this happens in an isolated system, it will increase the temperature of the system, and during the increase, the system is not in thermal equilibrium; but eventually the system will settle to a uniform temperature. In a system prepared as a block of ice floating in a bath of hot water, and then isolated, the ice can melt; during the melting, the system is not in thermal equilibrium; but eventually its temperature will become uniform. Such changes in isolated systems are irreversible in the sense that while such a change will occur spontanteously whenever the system is prepared in the same way, the reverse change will never occur spontanteously within the isolated system; this is a large part of the content of the second law of thermodynamics. Truly isolated systems hardly occur in nature, and nearly always are artificially prepared.
Read more about this topic: Thermal Equilibrium
Famous quotes containing the words change, internal, state, isolated and/or system:
“I guess it was easier for her to change her name than for her whole family to change theirs.”
—Vina Delmar, U.S. novelist, playwright. Lucy (Irene Dunne)
“We have our difficulties, true; but we are a wiser and a tougher nation than we were in 1932. Never have there been six years of such far flung internal preparedness in all of history. And this has been done without any dictator’s power to command, without conscription of labor or confiscation of capital, without concentration camps and without a scratch on freedom of speech, freedom of the press or the rest of the Bill of Rights.”
—Franklin D. Roosevelt (1882–1945)
“Having behind us the producing masses of this nation and the world, supported by the commercial interests, the labor interests, and the toilers everywhere, we will answer their demand for a gold standard by saying to them: You shall not press down upon the brow of labor this crown of thorns, you shall not crucify mankind upon a cross of gold.”
—Administration in the State of Neva, U.S. public relief program (1935-1943)
“An isolated outbreak of virginity ... is a rash on the face of society. It arouses only pity from the married, and embarrassment from the single.”
—Charlotte Bingham (b. 1942)
“Short of a wholesale reform of college athletics—a complete breakdown of the whole system that is now focused on money and power—the women’s programs are just as doomed as the men’s are to move further and further away from the academic mission of their colleges.... We have to decide if that’s the kind of success for women’s sports that we want.”
—Christine H. B. Grant, U.S. university athletic director. As quoted in the Chronicle of Higher Education, p. A42 (May 12, 1993)