Change of Internal State of An Isolated System
If an isolated system is left long enough, it will reach a state of thermal equilibrium, in which its temperature will be uniform throughout, but not necessarily a state of thermodynamic equilibrium, if there is some structural barrier that can prevent some possible processes in the system from reaching equilibrium. An isolated system can change its temperature or its spatial distribution of temperature by changing the state of Longley, R.G. Van Name, Longmans, Green & Co., New York, 1928, volume 1, pages 55-353, particularly pages 144-150. A system prepared as a mixture of petrol vapour and air can be ignited by a spark and produce carbon dioxide and water; if this happens in an isolated system, it will increase the temperature of the system, and during the increase, the system is not in thermal equilibrium; but eventually the system will settle to a uniform temperature. In a system prepared as a block of ice floating in a bath of hot water, and then isolated, the ice can melt; during the melting, the system is not in thermal equilibrium; but eventually its temperature will become uniform. Such changes in isolated systems are irreversible in the sense that while such a change will occur spontanteously whenever the system is prepared in the same way, the reverse change will never occur spontanteously within the isolated system; this is a large part of the content of the second law of thermodynamics. Truly isolated systems hardly occur in nature, and nearly always are artificially prepared.
Read more about this topic: Thermal Equilibrium
Famous quotes containing the words change of, change, internal, state, isolated and/or system:
“When man has nothing but his will to assert—even his good-will—it is always bullying. Bolshevism is one sort of bullying, capitalism another: and liberty is a change of chains.”
—D.H. (David Herbert)
“We think that we can change our clothes only.”
—Henry David Thoreau (1817–1862)
“We have our difficulties, true; but we are a wiser and a tougher nation than we were in 1932. Never have there been six years of such far flung internal preparedness in all of history. And this has been done without any dictator’s power to command, without conscription of labor or confiscation of capital, without concentration camps and without a scratch on freedom of speech, freedom of the press or the rest of the Bill of Rights.”
—Franklin D. Roosevelt (1882–1945)
“If nationality is consent, the state is compulsion.”
—Henri-Frédéric Amiel (1821–1881)
“An isolated outbreak of virginity ... is a rash on the face of society. It arouses only pity from the married, and embarrassment from the single.”
—Charlotte Bingham (b. 1942)
“A person, seasoned with a just sense of the imperfections of natural reason, will fly to revealed truth with the greatest avidity: while the haughty Dogmatist, persuaded that he can erect a compleat system of Theology by the mere help of philosophy, disdains any further aid, and rejects this adventitious instructor.”
—David Hume (1711–1776)