Tabaco City is politically subdivided into 47 barangays. San Pedro became a barrio in 1952.
| Barangay | Barangay Captain |
|---|---|
| Agnas (San Miguel Island) | Vicente B. Bataller, Jr. |
| Bacolod | Danilo B. Brillantes |
| Bangkilingan | Jose C. Cepcon, Sr. |
| Bantayan | Arsenio B. Biglete |
| Baranghawon | Rene B. Realizan |
| Basagan | Gerardo Q. Barasona |
| Basud (Pob.) | Jaime E. Abaniel, Jr. |
| Bogñabong | Emerita B. Bognalos |
| Bombon (Pob.) | Ramon Mirasol, Sr. |
| Bonot | Julio B. Borromeo |
| San Isidro | Eduardo C. Buison |
| Buang | Rachelle B. Bongon |
| Buhian | Dionisio P. Ragodon |
| Cabagñan | Noel B. Bonaobra |
| Cobo | Wilson B. Bondoy |
| Comon | Flaviano B. Bueno |
| Cormidal | Maria Gracia B. Esmenda |
| Divino Rostro (Pob.) | Salvador V. Sabariza, Jr. |
| Fatima | Ruben V. Bualoy |
| Guinobat | Erwin B. Borlagdan |
| Hacienda | Odon B. Bobiles |
| Magapo | Regino B. Broncate |
| Mariroc | Mecilla Jarabe |
| Matagbac | Reynaldo B. Borromeo |
| Oras | Abraham A. Camata |
| Oson | Clara B. Boringot |
| Panal | Glenn B. Sanchez |
| Pawa | Danilo B. Carillo |
| Pinagbobong | Orlando B. Buendia |
| Quinale Cabasan (Pob.) | Juan Sia C. Pielago |
| Quinastillojan | Armando C. Buere |
| Rawis (San Miguel Island) | Preciosisima B. Tango |
| Sagurong (San Miguel Island) | Lourdes B. Brusola |
| Salvacion | Edgar B. Realizan |
| San Antonio | Asuncion B. Ranola |
| San Carlos | Virgilio Brinas |
| San Juan (Pob.) | Samuel C. Carinan |
| San Lorenzo | Felicitas B. Bongon |
| San Ramon | Edilberto T. Balingbing |
| San Roque | Salvacion E. Balingbing |
| San Vicente | Severino L. Brosas |
| Santo Cristo (Pob.) | Roderick P. Martires |
| Sua-Igot | Lilybeth B. Broña |
| Tabiguian | Lorenzo B. Flores |
| Tagas | Leticia B. Saba |
| Tayhi (Pob.) | Calixto C. Onrubia, Jr. |
| Visita (San Miguel Island) | Pedro B. Boboyo |
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